Issue #23549: Clarify confusion in heapq doc - accessing the mininmal element

Merge 3.4

The current documentation only mentions heap[0] as the smallest element in the
beginning, and not in any of the methods' docs. There's no method to access the
minimal element without popping it, and the documentation of nsmallest is
confusing because it may suggest that min() is the way to go for n==1.